Strong antiferromagnetic exchange between manganese phthalocyanine and ferromagnetic europium oxide

Strong antiferromagnetic exchange between manganese phthalocyanine and ferromagnetic europium oxide.

We report on the antiferromagnetic exchange coupling between a submonolayer of Mn(II)-phthalocyanine molecules and a ferromagnetic Eu(II)-oxide thin film. The exchange energy is larger by nearly two orders of magnitude compared to previous studies involving oxidic substrates.

Tetracyanide-bridged divanadium complexes: redox switching between strong antiferromagnetic and strong ferromagnetic coupling.

Reaction of [(Me3tacn)V(CF3SO3)3] (Me3tacn = N,N',N''-trimethyl-1,4,7-triazacyclononane) with LiCN in DMF results in oligomerization of cyanide to form [(Me3tacn)2V2(CN)4(mu-C4N4)]. The structure of this binuclear complex features a planar tetracyanide unit bridging two VIV centers via imido type linkages. The conjugated pathway provided by the bridging ligand leads to strong antiferromagnetic ...

Coercivity and exchange bias of ferromagnetic/antiferromagnetic multilayers

For a model system consisting of a ferromagnetic layer exchange coupled to an antiferromagnetic layer with a compensated interface, detailed mean-field-type calculations are performed. Both the coercive field and the exchange bias field are calculated. For the coercive field, a rather broad enhancement around the Néel temperature TN of the antiferromagnetic layer is found irrespective of whethe...

Hall Resistivity in Ferromagnetic Manganese-Oxide Compounds

Temperature-dependence and magnetic field-dependence of the Hall effect and the magnetic property in manganese-oxide thin films are studied. The spontaneous magnetization and the Hall resistivity are obtained for a various of magnetic fields over all the temperature. It is shown that the Hall resistivity in small magnetic field is to exhibit maximum near the Curie point, and strong magnetic fie...

Exchange coupling induced antiferromagnetic-ferromagnetic transition in Pr0.5Ca0.5MnO3/La0.5Ca0.5MnO3 superlattices.